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Sahih Al-Bukhari Volume 1 The Book of Ablution (Wudu)

Sahih Bukhari – Volume 1 – Book 4 – P.139

(9) CHAPTER. What to say while going to the lavatory (water closet).

142.   Narrated Anas :   Whenever the Prophet, peace be upon him,  went to answer the call of nature, he used to say, “Allãh-umma inni a ‘üdhu bika minal khubuthi wal khãba’ ith [i.e., 0 Allah, I seek refuge with You from devils- males and females (or all offensive and wicked things, evil deeds etc.)].”